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銆€銆€閫氶亷寰挵(hu谩n)浼忓畨鏇茬窔鐨勬哀鍖栧嘲鍜岄倓鍘熷嘲鐨勫嘲楂�銆佸皪绋辨€с€佹哀鍖栧嘲鑸囬倓鍘熷嘲鐨勮窛闆�锛屼腑榛炰綅缃�锛屽彲鍒ゆ柗闆绘椿鎬х墿璩�(zh矛)鍦ㄩ浕妤佃〃闈㈠弽鎳�(y墨ng)鐨勫彲閫嗙▼搴﹀拰妤靛寲绋嬪害銆傚鏋滄哀鍖栬垏閭勫師鍙嶆噳(y墨ng)鐨勯亷闆讳綅 宸垾涓嶅ぇ鐨勫寲锛岄倓鍙互鎶婁竴灏嶆哀鍖栧嘲鑸囬倓鍘熷嘲涔嬮枔鐨勪腑榛炲€艰繎浼间綔鐐鸿┎鍙嶆噳(y墨ng)鐨勭啽鍔涘(xu茅)骞宠　闆讳綅鍊笺€�

銆€銆€鍙﹀鎭掗浕娴佸厖鏀鹃浕鐨勯浕澹撳閲忔洸绶氬井鍒嗗悗浠Q/dV 浣滅偤绺辫桓锛屾┇杌哥偤闆诲锛屽彲浠ョ嵅寰楄垏CV鏇茬窔鍗佸垎鐩镐技鐨勭祼(ji茅)鏋�锛屽叾瀵︽湰璩�(zh矛)骞舵矑鍗€(q奴)鍒ャ€�

銆€銆€寰挵(hu谩n)浼忓畨娉曡▓绠楅嫲闆㈠瓙鎿存暎绯绘暩(sh霉)

銆€銆€娉ㄦ剰锛氬儏閬╃敤浜庢摯鏁ｉ亷绋嬬偤鎺у埗姝ラ涓旈浕妤电偤鍙€嗛珨绯�锛屾鏅傛湁鍏紡

銆€銆€甯告韩鏅傦紝

銆€銆€寮忎腑锛孖p鐐哄嘲闆绘祦鐨勫ぇ灏忥紝n鐐哄弮鑸囧弽鎳�(y墨ng)鐨勯浕瀛愭暩(sh霉)锛孉鐐烘蹈鍏ユ憾娑蹭腑鐨勯浕妤甸潰绌�锛孎(xi脿n)鐐烘硶鎷夌甯告暩(sh霉)锛孌Li鐐篖i鍦ㄩ浕妤典腑鐨勬摯鏁ｇ郴鏁�(sh霉)锛寁鐐烘巸鎻忛€熺巼锛屸柍C0鐐哄弽鎳�(y墨ng)鍓嶅悗寰呮脯婵冨害鐨勮畩鍖�銆�

銆€銆€鍙互鎸夊涓嬫椹熶締瑷堢畻锛�

銆€銆€1銆佹脯閲忛浕妤垫潗鏂欏湪涓嶅悓鎺冩弿閫熺巼涓嬬殑寰挵(hu谩n)浼忓畨鏇茬窔;

銆€銆€2銆佸皣涓嶅悓鎺冩弿閫熺巼涓嬬殑宄板€奸浕娴佸皪鎺冩弿閫熺巼鐨勫钩鏂规牴浣滃湒;

銆€銆€3銆佸皪宄板€奸浕娴侀€茶绌嶅垎锛屾脯閲忔ǎ鍝佷腑閶扮殑婵冨害璁婂寲;

銆€銆€4銆佸皣鐩搁棞(gu膩n)鍙冩暩(sh霉)甯跺叆寮�(2)锛屽嵆鍙眰寰楁摯鏁ｇ郴鏁�(sh霉)銆�

銆€銆€闇€瑕佹敞鎰忕殑鏄�锛岀敱浜庝互涓嬪咕鍊嬪師鍥�锛屽叾娓緱鐨勭禃灏嶅€煎湪涓嶅悓鏂囩嵒涓笉鐩＄浉鍚�

銆€銆€闇€瑕佽┎鍙嶆噳(y墨ng)鏀舵摯鏁ｆ帶鍒�锛岃€屼笖寰挵(hu谩n)浼忓畨娓埌鐨勫寲瀛�(xu茅)鎿存暎绯绘暩(sh霉)骞堕潪闆绘サ鏉愭枡鍏�(n猫i)閮ㄦ湰寰佺殑闆㈠瓙鎿存暎绯绘暩(sh霉)(瑭崇窗鍏�(n猫i)瀹硅珛瑕嬫摯灞曢柋璁€)銆傞倓鏈夊氨鏄�锛屽鏋滄槸澶氬瓟绮夋湯闆绘サ锛屽叾鐪熷鍙嶆噳(y墨ng)闈㈢⿳閬犲ぇ浜庨浕妤靛咕浣曢潰绌嶏紝涓旈洠浠ョ簿纰烘脯閲�锛岀郸绲�(ji茅)鏋滃付渚嗗緢澶х殑涓嶇⒑瀹氭€с€�

銆€銆€鐣�(d膩ng)鐒�锛岄棞(gu膩n)浜庡惊鐠�(hu谩n)浼忓畨娉曞師鐞嗕娇鐢ㄧ瓑锛屾垜鍊戞渻鍙﹀瑭崇窗浠嬬垂銆�

銆€銆€鎭掗浕娴侀枔姝囨淮瀹氭妧琛�(sh霉)

銆€銆€鎭掗浕娴佸晱姝囨淮瀹氭妧琛�(sh霉)(galvanostaTIc intermittent TItraTIon technique)鐢卞痉鍦嬬瀛�(xu茅)瀹禬.Weppner鎻愬嚭锛� 鍩烘湰鍘熺悊鏄湪鏌愪竴鐗瑰畾鐠�(hu谩n)澧冧笅灏嶆脯閲忛珨绯绘柦鍔犱竴鎭� 瀹氶浕娴佸苟鎸佺簩(x霉)涓€娈垫檪鍟忓悗鍒囨柗瑭查浕娴�锛岃瀵熸柦鍔犻浕娴佹楂旂郴闆讳綅闅ㄦ檪闁撶殑璁婂寲浠ュ強寮涜鲍鍚庨仈鍒板钩琛＄殑闆诲锛岄€氶亷鍒嗘瀽闆讳綅闅ㄦ檪闁殑璁婂寲鍙互寰楀嚭闆绘サ閬� 绋嬮亷闆讳綅鐨勫紱璞俊鎭�锛岄€茶€屾帹娓拰瑷堢畻鍙嶆噳(y墨ng)鍕曞姏瀛�(xu茅)淇℃伅銆�

銆€銆€鐣�(d膩ng)楂旂郴婊胯冻濡備笅姊濅欢鏅傦紝鍙互瑷堢畻閶伴洟瀛愭摯鏁ｇ郴鏁�(sh霉)

銆€銆€1銆侀浕妤甸珨绯荤偤绛夋韩绲曠啽楂旂郴;

銆€銆€2銆侀浕妤甸珨绯诲湪鏂藉姞闆绘祦鏅傜劇楂旂⿳璁婂寲鑸囩浉璁�;

銆€銆€3銆侀浕妤甸熆鎳�(y墨ng)瀹屽叏鐢遍洟瀛愬湪闆绘サ鍏�(n猫i)閮ㄧ殑鎿存暎鎺у埗;

銆€銆€4銆佅勨墹L2/D锛孡鐐洪洟瀛愭摯鏁ｉ暦搴�;

銆€銆€5銆侀浕妤垫潗鏂欑殑闆诲瓙 闆诲皫(d菐o)閬犲ぇ浜庨洟瀛愰浕灏�(d菐o)绛夋浠�

銆€銆€瑷堢畻鍏紡濡備笅锛�

銆€銆€寮忎腑锛孌Li鐐衡€滃湪闆绘サ涓殑鍖栧(xu茅)鎿存暎绯绘暩(sh霉)锛孷m鐐烘椿鎬х墿璩�(zh矛)鐨勯珨绌�锛孉鐐烘蹈鍏ユ憾娑蹭腑鐨勭湡瀵﹂浕妤甸潰绌嶏紝F(xi脿n)鐐烘硶鎷夌甯告暩(sh霉)锛宯鐐哄弮鑸囧弽鎳�(y墨ng)鐨勯浕瀛愭暩(sh霉)鐩紝I0鐐烘淮瀹氶浕娴佸€�锛宒E/dx鐐洪枊璺浕浣嶅皪闆绘サ涓璍i婵冨害鏇茬窔涓婃煇婵冨害铏曠殑鏂滅巼(鍗冲韩渚栨淮瀹氭洸绶�)锛宒E/dt1/2鐐烘サ鍖栭浕澹撳皪鏅傞枔骞虫柟鏍规洸绶氱殑鏂滅巼銆�

銆€銆€鍒╃敤GITT鏂规硶娓噺闆绘サ鏉愭枡涓殑閶板寲瀛�(xu茅)鎿存暎绯绘暩(sh霉)鍩烘湰閬庣▼濡備笅锛氬湪闆绘睜鍏呮斁闆婚亷绋嬩腑鐨勬煇涓€ 鏅傚埢锛屾柦鍔犲井灏忛浕娴佸苟鎭掑畾涓€娈垫檪闁撳悗鍒囨柗;瑷橀寗闆绘祦鍒囨柗鍚庣殑闆绘サ闆讳綅闅ㄦ檪闁撶殑璁婂寲;鍋氬嚭妤靛寲闆诲灏嶆檪闁撳钩鏂规牴鏇茬窔锛屽嵆dE/dt1/2鏇茬窔;娓噺搴緰婊村畾鏇茬窔锛屽嵆dE/dx鏇茬窔;浠ｅ叆鐩搁棞(gu膩n)鍙冩暩(sh霉)锛屽埄鐢ㄥ叕寮忔眰瑙ｆ摯鏁ｇ郴鏁�(sh霉)銆�

銆€銆€鎭掗浕鍕㈤枔姝囨淮瀹氭妧琛�(sh霉)

銆€銆€鎭掗浕浣嶉枔姝囨淮瀹氭妧琛�(sh霉)(potentiostatic intermittent titration technique)鏄€氶亷鐬檪鏀硅畩闆绘サ闆讳綅骞舵亽瀹� 瑭查浕浣嶅€硷紝鍚屾檪瑷橀寗闆绘祦闅ㄦ檪闁撹畩鍖栫殑娓噺鏂规硶銆傞€氶亷鍒嗘瀽闆绘祦闅ㄦ檪闁撶殑璁婂寲鍙互寰楀嚭闆绘サ閬庣▼闆讳綅寮涜鲍淇℃伅浠ュ強鍏跺畠鍕曞姏瀛�(xu茅)淇℃伅锛� 椤炰技浜庢亽闆讳綅闅� 韬�锛屽彧鏄疨ITT鏄闆讳綅榛炴脯閲�銆�

銆€銆€浣跨敤鎭掗浕浣嶉枔姝囨淮瀹氭妧琛�(sh霉)娓噺閶伴洟瀛愬寲瀛�(xu茅)鎿存暎绯绘暩(sh霉)鍏紡濡備笅锛�

銆€銆€寮忎腑锛宨鐐洪浕娴佸€�锛宼鐐烘檪闁擄紝鈻砆鐐哄祵鍏ラ浕妤电殑闆婚噺锛孌Li鐐篖i鍦ㄩ浕妤典腑鐨勬摯鏁ｇ郴鏁�(sh霉)锛宒鐐烘椿鎬х墿璩�(zh矛)鐨勫帤搴�銆�

銆€銆€鍩烘湰鎿嶄綔濡備笅锛氫互鎭掑畾闆讳綅姝ラ暦鐬枔鏀硅畩闆� 妤甸浕浣�锛岃閷勯浕娴侀毃鏅傞枔鐨勮畩鍖�;鍒╃敤ln(i)涓€t鏇茬窔;鎴彇ln(i)涓€t鏇茬窔绶氭€ч儴鍒嗙殑鏁�(sh霉)鎿�(j霉)锛屾眰鏂滅巼鍗冲彲姹傚嚭閶伴洟瀛愬寲瀛�(xu茅)鎿存暎绯绘暩(sh霉)銆�

銆€銆€闆讳綅寮涜鲍鎶€琛�(sh霉)

銆€銆€闆讳綅寮涜鲍鎶€琛�(sh霉)(potential relax technique)鏄湪闆绘睜鑸囧鐣岀劇鐗╄唱(zh矛)鍜岃兘閲忎氦鎻涚殑姊濅欢涓嬬爺绌堕浕妤甸浕 鍕㈤毃鏅傞枔鐨勮畩鍖栭棞(gu膩n)绯�锛岃┎鏂规硶灞簬闆绘祦闅庤簫娓噺鏂� 娉曚腑鐨勬柗闆绘祦娉曪紝鑸嘒ITT瀵﹂鏂规硶涓€鑷�锛屼笉鍚岀殑鏄垎鏋愬紱璞亷绋嬩腑鐨勯浕浣嶈畩鍖�銆傝┎鏂规硶鏈€鏃╃敱涓湅绉戝(xu茅)闄㈢墿鐞嗙爺绌舵墍鐜嬫叾绛夐亱鐢ㄤ簬閶伴洟瀛愰浕姹犻浕妤垫潗鏂欎腑鐨勯洟瀛愭摯鏁ｅ嫊鍔涘(xu茅)鐮旂┒銆�

銆€銆€瑷堢畻鍏紡鐐猴細

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